In a semiconducting material, if the charge carriers originate from impurity atoms which are doped to the original material, then this type of semiconductor is known as extrinsic or impure semiconductor.
EXTRINSIC OR IMPURE SEMICONDUCTORS
In
a semiconducting material, if the charge carriers originate from impurity atoms
which are doped to the original material, then this type of semiconductor is
known as extrinsic or impure semiconductor.
It
is also known as doped semiconductor.
Extrinsic
semiconductor is obtained by adding trivalent or pentavalent impurity atoms to
a tetravalent semiconductor. The electrical properties of pure semiconductors
can be easily changed even with the addition of very little amount of
impurities.
Doping
The
addition of impurities to a pure semiconductor is known as doping and added
impurity is called as doping agent or dopant.
The addition of impurities increases the number of free electrons and holes in semiconductor and hence increases its electrical conductivity.
Some
of the common doping agents are arsenic, antimony, phosphorus, gallium,
aluminum and boron. These elements have either five or three valence electrons
in the outermost orbit.
Advantages of Extrinsic
semiconductors
i.
Electrical conductivity is high.
ii.
Electrical conductivity can be altered to any desired ΠΟΙ value by controlling
of doping concentration.
iii.
Electrical conductivity is not a function of temperature.
Types of Extrinsic semiconductors
The extrinsic semiconductors are classified into two types based on the type of impurity added. (Fig 3.6)
(i)
n-type semiconductor
(ii)
p-type semiconductor

Physics for Electronics Engineering: Unit III: Semiconductors and Transport Physics : Tag: : Doping, Advantages, Types - Extrinsic or Impure Semiconductors
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